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PUBLICATIONS

G. Smeureanu, A. Aggarwal, C. E. Soll, J. Arijeloye, Erik Malave, C. M. Drain Chem. Eur. J. 2009, 15, 12133 – 12140. “ Enhanced Catalytic Activity and Unexpected Products from the Oxidation of Cyclohexene by Organic Nanoparticles of 5,10,15,20-Tetrakis-(2,3,4,5,6-pentafluorophenyl)porphyrinatoiron (III) in Water by Using O2

C. M. Drain, S. Singh, D. Samaroo, S. Thompson, M. Vinodu, J. P. C. Tome, Proc. Soc. Photo-Optical Instrumentation Engineers-SPIE 2009, 7380, 73902K-1-9. “New Porphyrin  Glyco-conjugates”

A. Falber, B. P. Burton-Pye, I. Radivojevic, L. Todaro, R. Saleh, L. C. Francesconi, C. M. Drain Eur. J. Inorg. Chem. 2009, 2459–2466.Ternary Porphyrinato Hf(IV) and Zr(IV) Polyoxometalate Complexes”

C.M. Drain, A. Varotto, I. Radivojevic Chem. Reviews 2009, 109, 1630–1658. “Self-Organized Porphyrinic Materials”

J. Samson, A. Varotto, P. C. Nahirney, A. Toschi, I. Piscopo, C. M. Drain, ACS Nano 2009, 3 339-344. “Fabrication of Metal Nanoparticles Using Toroidal Plasmid DNA as a Sacrificial Mold”

A. Varotto, L. Todaro, M. Vinodu, J. Koehne, G.-y. Liu, C.M. Drain, Chem. Com. 2008, 4921-4923. “Self-organization of a new fluorous porphyrin and C60 films on indium-tin-oxide electrodes”

S. Thompson,  X. Chen, L. Hui, A. Toschi, D. A. Foster, C.M. Drain, Photochem. Photobiol. Sci. 2008, 7, 1415-1421. “Low Concentrations of a non-hydrolysable tetra-S-glycosylated porphyrin and low light induces apoptosis in human breast cancer cells via stress of the endoplasmic reticulum”

N. Stevens, N. O’Connor, H. Vishwasrao. D. Samaroo, E.R. Kandel, D.L. Akins, C.M. Drain, N.J. Turro, J. Am. Chem. Soc. 2008130, 7182-7183.  “Two Color RNA Intercalating Probe for Cell Imaging Applications”

W. K. Serem, A. Varotto, G. Castro, C. M. Drain, J. C. Garno NOBCChE Proceedings 2008, 2-9. “Investigation of the Vibrational Response of Individual Nanoparticles using AFM with Magnetic Sample Modulation”

Y.-H. Chan, A.E. Schuckman, L.M. Perez, M. Vinodu, C.M. Drain, J.D. Batteas, J. Phys. Chem. C., 2008; 112, 6110-6118. “Synthesis and Characterization of a Thiol-tethered Tripyridyl Porphyrin on Au(111)”

G. Bazzan, W. Smith, L.C. Francesconi, C.M. Drain, Langmuir, 2008, 24, 3244-3249. “Electrostatic Self-Organization of Robust Porphyrin-Polyoxometalate Films”

A. Falber, L.Todaro, I. Goldberg, M.V. Favilla, C. M. Drain Inorg. Chem. 2008, 47, 454-467 “Routes to New Hafnium(IV)Tetra-aryl Porphyrins and Crystal Structures of Unusual Phosphate, Sulfate, and Peroxide Bridged Dimers”

T.S. Balaban, N. Berova, C.M. Drain, R. Hauschild, H. Kalt, S. Lebedkin, J.-M. Lehn, X. Huang, F. Nifaitis, G. Pescitelli, V.I. Prokhorenko, G. Riedel, G. Smeureanu, J. Zeller, Chem. Eur. J. 2007, 13, 8411-8427. “Syntheses and Energy Transfer in Multiporphyrin Arrays Self-Assembled with Hydrogen Bonding Recognition Groups: Towards Artificial Light-Harvesting Devices

D. Samaroo, M. Vinodu, X. Chen, C.M. Drain, J. Combi. Chem. 2007, 9, 998-1011. “Meso-tetra(pentafluorophenyl)porphyrin is an Efficient Platform for Combinatorial Synthesis, and the Selection of New Photodynamic Therapeutics using a Cancer Cell Line”

C. M. Drain, G. Smeureanu,  S. Patel, X. Gong, J. Garno, J. Arijeloye, New J. Chem. 2006, 30, 1834-1843.  “Porphyrin Nanoparticles as Supramolecular Systems”

D. Samaroo, C. E. Soll, L. J. Todaro, C. M. Drain Org. Lett. 2006, 8, 4985 – 4988. “Efficient microwave-assisted synthesis of amine substituted pentafluorophenylporphyrin”

K.F. Cheng, N. A. Thai, L. C. Teague, K. Grohmann,  C.M. Drain, Inorg. Chem. 2006, 45, 6928-6932. “Tessellation of Porphyrazines with Porphyrins by Design”

J. M. Helt, C. M. Drain, G Bazzan. J. Am. Chem. Soc. 2006, 128(29); 9371-9377. “Stamping Patterns of Insulated Gold Nanowires with Self-Organized Ultrathin Polymer Films”

J.C. Garno, C. Xu, G. Bazzan, J. D. Batteas, C. M. Drain, ACS Symposium series: Metal-Containing and Metallo-Supramolecular Polymers and Materials, U.S. Schubert, G.R. Newcome, I. Manners eds. 2006, 928, 168-183; American Chemical Society, Washington, DC. Book Chapter: “Designing Supramolecular Porphyrin Arrays for Surface Assembly and Patterning of Optoelectronic Materials”

C. Xu, T. Wu, C. M. Drain, J. D. Batteas, M. J. Fasolka, K. L. Beers, Macromolecules, 2006, 39, 3359-3364. “Effect of Block Length on Solvent Response of Block Copolymer Brushes: Combinatorial Study with Block Copolymer Brush Gradients”

M. Vittadello, P. E. Stallworth, F. M. Alamgir, S. Suarez, S. Abbrent, C. M. Drain, V. Di Noto, S. G. Greenbaum, Inorg. Chim. Acta 2006, 339, 2513-2518.  "Polymeric d-MgCl2 nanoribbons"

C. Xu, T. Wu, J. D. Batteas, C. M. Drain, K. L. Beers, M. J. Fasolka, Applied Surface Science, 2006, 252 (7), 2529-2534. "Surface-grafted block copolymer gradients: Effect of block length on solvent response"

C. Xu, T. Wu, Y. Mei, C.M. Drain, J.D. Batteas, K. L. Beers, Langmuir, 2005; 21, 11136-11140. “Synthesis and Characterization of Tapered Copolymer Brushes via Surface-Initiated Atom Transfer Radical Copolymerization”

K.F. Cheng, N.A. Thai, L.C. Teague, K. Grohmann, C.M. Drain, Chem. Comm. 2005, 4678-4680. “Supramolecular squares of porphyrazines”

C.M. Drain, G. Bazzan, T. Milic, M. Vinodu, J. C. Goeltz. Israel J. Chem. 2005, 45, 255-269. Formation and Applications of Stable 10 nm to 500 nm Supramolecular Porphyrinic Materials

C. Xu, T. Wu, C. M. Drain, J. D. Batteas, K. L. Beers Macromolecules 2005, 38, 6-8. “Microchannel Confined Surface-Initiated Polymerization”

C.M. Drain, I. Goldberg, I. Sylvain, A. Falber Top. Curr. Chem. 2005, 245, 55–88. “Synthesis and Applications of Supramolecular Porphyrinic Materials”

X. Chen and C.M. Drain, Drug Design Reviews - Online, 2004, 1(3), 215-234. Bentham Science Publishers Ltd. (http://www.bentham.org/ctmc/index.html ) “Photodynamic Therapy Using Carbohydrate Conjugated Porphyrins”

X. Chen, L. Hui, D. A. Foster, C. M. Drain,  Biochemistry 2004, 43, 10918-10929. "Efficient Synthesis and Photodynamic Activity of Porphyrin-Saccharide Conjugates: Targeting and Incapacitating Cancer Cells”

<!--[if !supportLists]-->C. Xu, T. Wu, C. M. Drain, J. D. Batteas, K. L. Beers ACS Polymer Reprints, 2004, 45(2), 667-668.  Synthesis of Gradient Copolymer Brushes via Surface Initiated Atom Transfer Radical Copolymerization”

<!--[if !supportLists]-->C.M. Drain, T. Milic, J. C. Garno, G. Smeureanu, J.D. Batteas  ACS Polymer Reprints 2004, 45(1), 346-347.  "Organizing Self-Assembled Porphyrin Arrays On Metal And Glass Surfaces"

<!--[if !supportLists]-->T. Milic, J. C. Garno, G. Smeureanu, J. D. Batteas, C. M. Drain, Langmuir, 2004, 20, 3974-3983 ‘Self-Organization of Self-Assembled Tetrameric Porphyrin Arrays on Surfaces”

<!--[if !supportLists]-->C.M. Drain, G. Smeareanu, J.D. Batteas, S. Patel. Book chapter: Dekker Encyclopedia of Nanotechnology, “Self-assembled Porphyrin Arrays on Surfaces,” Vol 5. pp3481-3502. J.A. Schwartz, C.I. Contescu, K. Putyera, Eds.; Marcel Dekker, Inc. New York, 2004.

<!--[if !supportLists]-->J. M. Helt, C. M. Drain, J. D. Batteas, J. Am. Chem. Soc. 136, 2004, 628-634. “A Bench Top Method for the Fabrication and Patterning of Nanoscale Structures on Polymers”

<!--[if !supportLists]-->C.M. Drain, X. Chen. Book chapter: Encyclopedia of Nanoscience & Nanotechnology “Self-Assembled Porphyrinic NanoarchitecturesVol. 9, pp593-616. H.S. Nalwa Edt., American Scientific Press, 2004.

<!--[if !supportLists]-->J. L. Retsek, C. M. Drain, C. Kirmaier,D. J. Nurco, C. J. Medforth, K. M. Smith,  V. S. Chirvony, J. Fajer, D. Holten. J. Am. Chem. Soc. 2003, 125, 9787-9800.  ”Photoinduced Axial Ligation and Deligation Dynamics of Nonplanar Nickel Dodecaarylporphyrins”

<!--[if !supportLists]-->C.M. Drain, K.F. Cheng, K. Grohmann Inorg. Chem. 2003, 42, 2075-2083. ”Porphyrins Linked Directly to the 5,5’ Positions of 2, 2’- Bipyridine: A New Supramolecular Building Block and Switch”

<!--[if !supportLists]-->X. Gong, T. Milic, C. Xu, J. D. Batteas, C. M. Drain J. Am. Chem. Soc. 2002, 124, 14290-14291. “Preparation and characterization of porphyrin nanoparticles”

<!--[if !supportLists]-->C.M. Drain, J.T. Hupp, K Suslick, M. Waseleiwski, J. Porph. Phthal.  2002, 6, in press.  “A perspective on four new porphyrin-based functional materials and devices”

<!--[if !supportLists]--> <!--[endif]-->T. N. Milic, N. Chi, D. G. Yablon, G. W. Flynn, J. D. Batteas, C. M. Drain Angew. Chem., Int. Ed. Engl. 2002,  41, 2117-2119. “Controlled Hierarchical Self-Assembly and Deposition of Nanoscale Photonic Materials”

<!--[if !supportLists]-->C.M. Drain Proc. Natl. Acad. Sci., USA, 2002, 99, 5178-5182. “Self-organization of self-assembled photonic materials into functional devices: Photo-switched conductors” (Invited contribution to special issue on self-assembly)

<!--[if !supportLists]-->C.M. Drain, J.D. Batteas, G.W. Flynn, T. Milic, N. Chi, D.G. Yablon, H. SommersProc. Natl. Acad. Sci., USA. 2002, 99, 6498-6502 (Invited contribution to a special issue on Nanotechnology) Self-Assembly of Supramolecular Porphyrin Arrays that Self-Organize into Nanoscale Optical and Magnetic Materials

<!--[if !supportLists]--> <!--[endif]-->X. Shi, K. M. Barkigia, J. Fajer, C. M. Drain, J. Org. Chem. 2001, 66, 6513-6522. “Design and Synthesis of Porphyrins Bearing Rigid Hydrogen Bonding Motifs: Highly Versatile Building Blocks for Self-Assembly of Polymers and Discrete Arrays”

<!--[if !supportLists]-->P. Pasetto, X. Chen, C. M. Drain, R.W. Franck, Chem. Commun, 2001, 82-83.  “Synthesis of hydrolytically stable porphyrin C- and S- glycoconjugates in high yields”

<!--[if !supportLists]--> <!--[endif]-->X. Shi, F. Nifiatis, T. Milic, and C. M. Drain, Chem. Commun. 2001, 287-288.Self-assembled multiporphyrin arrays mediated by self-complementary quadruple hydrogen bond motifs”

<!--[if !supportLists]--> <!--[endif]-->C. M. Drain, X. Gong, V. Ruta, C. E. Soll, and P. F. Chicoineau J. Combin. Chem. 1999, 1, 286-290. “Combinatorial Synthesis and Modification of Functional Porphyrin Libraries: Identification of New, Amphipathic Motifs for Biomolecule Binding”

<!--[if !supportLists]-->C.M. Drain, F. Nifiatis, A. Vasenko, J. Batteas, Angew. Chem., Int. Ed. 1998, 37, 2344-2347. Ibid. Angew. Chem. 1998, 110, 2474.  Porphyrin tessellation by design:  Metal mediated self-assembly of large arrays and tapes.*  See “Materials to Meet Tomorrow’s Challenges” Cover story of C&E News 1998, page 35-44, June 8.

<!--[if !supportLists]-->C.M. Drain, S. Gentemann, J.A. Roberts, N.Y. Nelson, C.J. Medforth, S. Jai, M.C. Simpson, K.M. Smith, J. Fajer, J.A. Shelnutt, and D. Holten.  J. Am. Chem. Soc. 1998, 120, 3781-3791.  “Picosecond to microsecond photodynamics of a nonplanar nickel porphyrin: Solvent dielectric and temperature effects.”

<!--[if !supportLists]-->C.M. Drain and X. Gong. J.C.S., Chem. Commun. 1997, 2117-2118.  “Synthesis of meso substituted porphyrins in air without solvents or catalysts”

<!--[if !supportLists]--> <!--[endif]-->C. M. Drain, C. Kirmaier, C. Medforth, D. Nurco, K.M. Smith, and D. Holten.  J. Phys. Chem. 1996, 100 11983-11993.  “Dynamic photophysical properties of conformationally distorted nickel(II) porphyrins 1.  Nickel(II) dodecaphenylporphyrin.”

<!--[if !supportLists]-->C.M. Drain, K.C. Russell, and J.-M. Lehn. J. Chem. Soc., Chem. Commun. 1996, 337-338.  “Self-assembly of a multi-porphyrin supramolecular macrocycle by hydrogen-bond molecular recognition.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain and J.-M. Lehn. J. Chem. Soc., Chem. Commun. 1994, 2313-2315.  “Self-assembly of square multiporphyrin arrays by metal ion coordination.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain, D. Wade, P. Fehlner, and R.B. Merrifield. 13th Amer. Pept. Symp. 1993, S2, 93.  “The role of lysine-7 in the voltage gating, ion selectivity, and hemolytic activity of melettin pores.”

<!--[if !supportLists]-->C.M. Drain, R. Fischer, E. Nolen, and J.-M. Lehn.  J. Chem. Soc., Chem. Commun. 1993, 243-245.  “Self-assembly of a bis-porphyrin cage induced by molecular recognition between complementary hydrogen bonding sites.”

<!--[if !supportLists]-->C.M. Drain and D. Mauzerall. Biophys. J. 1992, 63, 1556-1563.  “Photogating of ionic currents across the lipid bilayer:  Hydrophobic ion conduction by an ion chain mechanism.”

<!--[if !supportLists]--> <!--[endif]-->D. Mauzerall and C.M. Drain. Biophys. J. 1992, 63, 1544-1555.  “Photogating of ionic currents across the lipid bilayer:  Electrostatics of ions and dipoles inside the membrane.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain and D. Mauzerall.  Bioelectrochem. Bioenerg. 1990, 24, 263-266.  “An example of a working Charge Sensitive Ion Conductor (CSIC).”

<!--[if !supportLists]-->D. Wade, A. Boman, B. Wåhlin, C.M. Drain, D. Andreu, H.G. Boman, and R.B. Merrifield. Proc. Natl. Acad. Sci., USA 1990, 87, 4761-4765.  “All-D amino acid channel-forming antibiotic peptides.”

<!--[if !supportLists]-->C.M. Drain, D. Sable, and B.B. Corden. Inorg. Chem. 1990, 29, 1428-1433.  “The reactivity of 1,4,7,10,13-pentaazacyclohexadecane-14,16-dionato(2-) nickel(II) towards derivatives of methyl-coenzyme-M.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain and B.B. Corden. Inorg. Chem. 1989, 28, 4374-4376.  “Synthesis and characterization of copper (II)  5,10,15,20-tetrakis(2,6-dipivalamidophenyl)porphyrin:  a bis-picket-fence porphyrin.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain, B. Christensen, and D. Mauzerall. Proc. Natl. Acad. Sci., USA 1989, 86, 6959-6962.  “Photogating of ionic currents across the lipid bilayer.”

<!--[if !supportLists]--> <!--[endif]-->C.M. Drain, D. Sable, and B.B. Corden. Inorg. Chem. 1988, 27, 2396-2398.  “Nickel(II) dioxo[16]ane-N5  induced methane formation from methyl-coenzyme-M.”

C.M. Drain and B.B. Corden.  J. Chem. Educ. 1987, 64, 441-443.  “Reversible oxygenation of oxygen transport proteins.”

C.M. Drain and B.B. Corden.  J. Chem. Educ. 1987, 64, 441-443.  “Reversible oxygenation of oxygen transport proteins.”